mpdkilljob.py: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/mpdkilljob.py - from package: mpich2

You may install the required package with command yum install {package}
Error in other languages:
mpdkilljob.py: bevel nie gevind nie
mpdkilljob.py: comandă negăsită
mpdkilljob.py: comando não encontrado
mpdkilljob.py: commande introuvable
mpdkilljob.py: command not found
mpdkilljob.py: käsku ei ole
mpdkilljob.py: không tìm thấy lệnh
mpdkilljob.py: komanda nerasta
mpdkilljob.py: Kommando nicht gefunden.
mpdkilljob.py: kommandot finns inte
mpdkilljob.py: komut yok
mpdkilljob.py: nie znaleziono polecenia
mpdkilljob.py: níor aimsíodh an t-ordú
mpdkilljob.py: no se encontró la orden
mpdkilljob.py: no s'ha trobat l'ordre
mpdkilljob.py: opdracht niet gevonden
mpdkilljob.py: parancs nem található
mpdkilljob.py: perintah tidak ditemukan
mpdkilljob.py: príkaz nenájdený
mpdkilljob.py: příkaz nenalezen
mpdkilljob.py: команда не найдена
mpdkilljob.py: командата не е открита
mpdkilljob.py: 命令找不到
mpdkilljob.py: コマンドが見つかりません