sss_debuglevel: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/sbin/sss_debuglevel - from package: sssd-tools

You may install the required package with command yum install {package}

On Debian possible default full paths are:

/usr/sbin/sss_debuglevel - from package: sssd-tools

You may install the required package with command apt-get install {package}
Error in other languages:
sss_debuglevel: bevel nie gevind nie
sss_debuglevel: comandă negăsită
sss_debuglevel: comando não encontrado
sss_debuglevel: commande introuvable
sss_debuglevel: command not found
sss_debuglevel: käsku ei ole
sss_debuglevel: không tìm thấy lệnh
sss_debuglevel: komanda nerasta
sss_debuglevel: Kommando nicht gefunden.
sss_debuglevel: kommandot finns inte
sss_debuglevel: komut yok
sss_debuglevel: nie znaleziono polecenia
sss_debuglevel: níor aimsíodh an t-ordú
sss_debuglevel: no se encontró la orden
sss_debuglevel: no s'ha trobat l'ordre
sss_debuglevel: opdracht niet gevonden
sss_debuglevel: parancs nem található
sss_debuglevel: perintah tidak ditemukan
sss_debuglevel: príkaz nenájdený
sss_debuglevel: příkaz nenalezen
sss_debuglevel: команда не найдена
sss_debuglevel: командата не е открита
sss_debuglevel: 命令找不到
sss_debuglevel: コマンドが見つかりません