polB_openmpi: command not found

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/lib64/openmpi/bin/polB_openmpi - from package: openmx-openmpi

You may install the required package with command yum install {package}

Error in other languages:
polB_openmpi: bevel nie gevind nie
polB_openmpi: comandă negăsită
polB_openmpi: comando não encontrado
polB_openmpi: commande introuvable
polB_openmpi: command not found
polB_openmpi: käsku ei ole
polB_openmpi: không tìm thấy lệnh
polB_openmpi: komanda nerasta
polB_openmpi: Kommando nicht gefunden.
polB_openmpi: kommandot finns inte
polB_openmpi: komut yok
polB_openmpi: nie znaleziono polecenia
polB_openmpi: níor aimsíodh an t-ordú
polB_openmpi: no se encontró la orden
polB_openmpi: no s'ha trobat l'ordre
polB_openmpi: opdracht niet gevonden
polB_openmpi: parancs nem található
polB_openmpi: perintah tidak ditemukan
polB_openmpi: príkaz nenájdený
polB_openmpi: příkaz nenalezen
polB_openmpi: команда не найдена
polB_openmpi: командата не е открита
polB_openmpi: 命令找不到
polB_openmpi: コマンドが見つかりません