pt-index-usage: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/bin/pt-index-usage - from package: percona-toolkit

You may install the required package with command apt-get install {package}
Error in other languages:
pt-index-usage: bevel nie gevind nie
pt-index-usage: comandă negăsită
pt-index-usage: comando não encontrado
pt-index-usage: commande introuvable
pt-index-usage: command not found
pt-index-usage: käsku ei ole
pt-index-usage: không tìm thấy lệnh
pt-index-usage: komanda nerasta
pt-index-usage: Kommando nicht gefunden.
pt-index-usage: kommandot finns inte
pt-index-usage: komut yok
pt-index-usage: nie znaleziono polecenia
pt-index-usage: níor aimsíodh an t-ordú
pt-index-usage: no se encontró la orden
pt-index-usage: no s'ha trobat l'ordre
pt-index-usage: opdracht niet gevonden
pt-index-usage: parancs nem található
pt-index-usage: perintah tidak ditemukan
pt-index-usage: príkaz nenájdený
pt-index-usage: příkaz nenalezen
pt-index-usage: команда не найдена
pt-index-usage: командата не е открита
pt-index-usage: 命令找不到
pt-index-usage: コマンドが見つかりません