pmw.x: command not found

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/pmw.x - from package: quantum-espresso

You may install the required package with command yum install {package}

On Debian possible default full paths are:

/usr/bin/pmw.x - from package: quantum-espresso

You may install the required package with command apt-get install {package}

Error in other languages:
pmw.x: bevel nie gevind nie
pmw.x: comandă negăsită
pmw.x: comando não encontrado
pmw.x: commande introuvable
pmw.x: command not found
pmw.x: käsku ei ole
pmw.x: không tìm thấy lệnh
pmw.x: komanda nerasta
pmw.x: Kommando nicht gefunden.
pmw.x: kommandot finns inte
pmw.x: komut yok
pmw.x: nie znaleziono polecenia
pmw.x: níor aimsíodh an t-ordú
pmw.x: no se encontró la orden
pmw.x: no s'ha trobat l'ordre
pmw.x: opdracht niet gevonden
pmw.x: parancs nem található
pmw.x: perintah tidak ditemukan
pmw.x: príkaz nenájdený
pmw.x: příkaz nenalezen
pmw.x: команда не найдена
pmw.x: командата не е открита
pmw.x: 命令找不到
pmw.x: コマンドが見つかりません