gnunet-datastore: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/bin/gnunet-datastore - from package: gnunet

You may install the required package with command apt-get install {package}
Error in other languages:
gnunet-datastore: bevel nie gevind nie
gnunet-datastore: comandă negăsită
gnunet-datastore: comando não encontrado
gnunet-datastore: commande introuvable
gnunet-datastore: command not found
gnunet-datastore: käsku ei ole
gnunet-datastore: không tìm thấy lệnh
gnunet-datastore: komanda nerasta
gnunet-datastore: Kommando nicht gefunden.
gnunet-datastore: kommandot finns inte
gnunet-datastore: komut yok
gnunet-datastore: nie znaleziono polecenia
gnunet-datastore: níor aimsíodh an t-ordú
gnunet-datastore: no se encontró la orden
gnunet-datastore: no s'ha trobat l'ordre
gnunet-datastore: opdracht niet gevonden
gnunet-datastore: parancs nem található
gnunet-datastore: perintah tidak ditemukan
gnunet-datastore: príkaz nenájdený
gnunet-datastore: příkaz nenalezen
gnunet-datastore: команда не найдена
gnunet-datastore: командата не е открита
gnunet-datastore: 命令找不到
gnunet-datastore: コマンドが見つかりません