gdal_merge_simple: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/bin/gdal_merge_simple - from package: dans-gdal-scripts

You may install the required package with command apt-get install {package}
Error in other languages:
gdal_merge_simple: bevel nie gevind nie
gdal_merge_simple: comandă negăsită
gdal_merge_simple: comando não encontrado
gdal_merge_simple: commande introuvable
gdal_merge_simple: command not found
gdal_merge_simple: käsku ei ole
gdal_merge_simple: không tìm thấy lệnh
gdal_merge_simple: komanda nerasta
gdal_merge_simple: Kommando nicht gefunden.
gdal_merge_simple: kommandot finns inte
gdal_merge_simple: komut yok
gdal_merge_simple: nie znaleziono polecenia
gdal_merge_simple: níor aimsíodh an t-ordú
gdal_merge_simple: no se encontró la orden
gdal_merge_simple: no s'ha trobat l'ordre
gdal_merge_simple: opdracht niet gevonden
gdal_merge_simple: parancs nem található
gdal_merge_simple: perintah tidak ditemukan
gdal_merge_simple: príkaz nenájdený
gdal_merge_simple: příkaz nenalezen
gdal_merge_simple: команда не найдена
gdal_merge_simple: командата не е открита
gdal_merge_simple: 命令找不到
gdal_merge_simple: コマンドが見つかりません