g_tcaf: command not found

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/g_tcaf - from package: gromacs

You may install the required package with command yum install {package}

On Debian possible default full paths are:

/usr/bin/g_tcaf - from package: gromacs

You may install the required package with command apt-get install {package}

Error in other languages:
g_tcaf: bevel nie gevind nie
g_tcaf: comandă negăsită
g_tcaf: comando não encontrado
g_tcaf: commande introuvable
g_tcaf: command not found
g_tcaf: käsku ei ole
g_tcaf: không tìm thấy lệnh
g_tcaf: komanda nerasta
g_tcaf: Kommando nicht gefunden.
g_tcaf: kommandot finns inte
g_tcaf: komut yok
g_tcaf: nie znaleziono polecenia
g_tcaf: níor aimsíodh an t-ordú
g_tcaf: no se encontró la orden
g_tcaf: no s'ha trobat l'ordre
g_tcaf: opdracht niet gevonden
g_tcaf: parancs nem található
g_tcaf: perintah tidak ditemukan
g_tcaf: príkaz nenájdený
g_tcaf: příkaz nenalezen
g_tcaf: команда не найдена
g_tcaf: командата не е открита
g_tcaf: 命令找不到
g_tcaf: コマンドが見つかりません