g_gmxdump: command not found

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/g_gmxdump - from package: gromacs

You may install the required package with command yum install {package}

Error in other languages:
g_gmxdump: bevel nie gevind nie
g_gmxdump: comandă negăsită
g_gmxdump: comando não encontrado
g_gmxdump: commande introuvable
g_gmxdump: command not found
g_gmxdump: käsku ei ole
g_gmxdump: không tìm thấy lệnh
g_gmxdump: komanda nerasta
g_gmxdump: Kommando nicht gefunden.
g_gmxdump: kommandot finns inte
g_gmxdump: komut yok
g_gmxdump: nie znaleziono polecenia
g_gmxdump: níor aimsíodh an t-ordú
g_gmxdump: no se encontró la orden
g_gmxdump: no s'ha trobat l'ordre
g_gmxdump: opdracht niet gevonden
g_gmxdump: parancs nem található
g_gmxdump: perintah tidak ditemukan
g_gmxdump: príkaz nenájdený
g_gmxdump: příkaz nenalezen
g_gmxdump: команда не найдена
g_gmxdump: командата не е открита
g_gmxdump: 命令找不到
g_gmxdump: コマンドが見つかりません