btrfs-vol: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/sbin/btrfs-vol - from package: btrfs-progs

You may install the required package with command yum install {package}
Error in other languages:
btrfs-vol: bevel nie gevind nie
btrfs-vol: comandă negăsită
btrfs-vol: comando não encontrado
btrfs-vol: commande introuvable
btrfs-vol: command not found
btrfs-vol: käsku ei ole
btrfs-vol: không tìm thấy lệnh
btrfs-vol: komanda nerasta
btrfs-vol: Kommando nicht gefunden.
btrfs-vol: kommandot finns inte
btrfs-vol: komut yok
btrfs-vol: nie znaleziono polecenia
btrfs-vol: níor aimsíodh an t-ordú
btrfs-vol: no se encontró la orden
btrfs-vol: no s'ha trobat l'ordre
btrfs-vol: opdracht niet gevonden
btrfs-vol: parancs nem található
btrfs-vol: perintah tidak ditemukan
btrfs-vol: príkaz nenájdený
btrfs-vol: příkaz nenalezen
btrfs-vol: команда не найдена
btrfs-vol: командата не е открита
btrfs-vol: 命令找不到
btrfs-vol: コマンドが見つかりません