catkin-build-debs-of-workspace: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/catkin-build-debs-of-workspace - from package: catkin

You may install the required package with command yum install {package}
Error in other languages:
catkin-build-debs-of-workspace: bevel nie gevind nie
catkin-build-debs-of-workspace: comandă negăsită
catkin-build-debs-of-workspace: comando não encontrado
catkin-build-debs-of-workspace: commande introuvable
catkin-build-debs-of-workspace: command not found
catkin-build-debs-of-workspace: käsku ei ole
catkin-build-debs-of-workspace: không tìm thấy lệnh
catkin-build-debs-of-workspace: komanda nerasta
catkin-build-debs-of-workspace: Kommando nicht gefunden.
catkin-build-debs-of-workspace: kommandot finns inte
catkin-build-debs-of-workspace: komut yok
catkin-build-debs-of-workspace: nie znaleziono polecenia
catkin-build-debs-of-workspace: níor aimsíodh an t-ordú
catkin-build-debs-of-workspace: no se encontró la orden
catkin-build-debs-of-workspace: no s'ha trobat l'ordre
catkin-build-debs-of-workspace: opdracht niet gevonden
catkin-build-debs-of-workspace: parancs nem található
catkin-build-debs-of-workspace: perintah tidak ditemukan
catkin-build-debs-of-workspace: príkaz nenájdený
catkin-build-debs-of-workspace: příkaz nenalezen
catkin-build-debs-of-workspace: команда не найдена
catkin-build-debs-of-workspace: командата не е открита
catkin-build-debs-of-workspace: 命令找不到
catkin-build-debs-of-workspace: コマンドが見つかりません