zpasswd: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/lib/zope2.13/bin/zpasswd - from package: zope2.13

You may install the required package with command apt-get install {package}
Error in other languages:
zpasswd: bevel nie gevind nie
zpasswd: comandă negăsită
zpasswd: comando não encontrado
zpasswd: commande introuvable
zpasswd: command not found
zpasswd: käsku ei ole
zpasswd: không tìm thấy lệnh
zpasswd: komanda nerasta
zpasswd: Kommando nicht gefunden.
zpasswd: kommandot finns inte
zpasswd: komut yok
zpasswd: nie znaleziono polecenia
zpasswd: níor aimsíodh an t-ordú
zpasswd: no se encontró la orden
zpasswd: no s'ha trobat l'ordre
zpasswd: opdracht niet gevonden
zpasswd: parancs nem található
zpasswd: perintah tidak ditemukan
zpasswd: príkaz nenájdený
zpasswd: příkaz nenalezen
zpasswd: команда не найдена
zpasswd: командата не е открита
zpasswd: 命令找不到
zpasswd: コマンドが見つかりません