xdg-autostart: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/bin/xdg-autostart - from package: obsession

You may install the required package with command apt-get install {package}
Error in other languages:
xdg-autostart: bevel nie gevind nie
xdg-autostart: comandă negăsită
xdg-autostart: comando não encontrado
xdg-autostart: commande introuvable
xdg-autostart: command not found
xdg-autostart: käsku ei ole
xdg-autostart: không tìm thấy lệnh
xdg-autostart: komanda nerasta
xdg-autostart: Kommando nicht gefunden.
xdg-autostart: kommandot finns inte
xdg-autostart: komut yok
xdg-autostart: nie znaleziono polecenia
xdg-autostart: níor aimsíodh an t-ordú
xdg-autostart: no se encontró la orden
xdg-autostart: no s'ha trobat l'ordre
xdg-autostart: opdracht niet gevonden
xdg-autostart: parancs nem található
xdg-autostart: perintah tidak ditemukan
xdg-autostart: príkaz nenájdený
xdg-autostart: příkaz nenalezen
xdg-autostart: команда не найдена
xdg-autostart: командата не е открита
xdg-autostart: 命令找不到
xdg-autostart: コマンドが見つかりません