virt-alignment-scan: command not found

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/virt-alignment-scan - from package: libguestfs-tools-c

You may install the required package with command yum install {package}

On Debian possible default full paths are:

/usr/bin/virt-alignment-scan - from package: libguestfs-tools

You may install the required package with command apt-get install {package}

Error in other languages:
virt-alignment-scan: bevel nie gevind nie
virt-alignment-scan: comandă negăsită
virt-alignment-scan: comando não encontrado
virt-alignment-scan: commande introuvable
virt-alignment-scan: command not found
virt-alignment-scan: käsku ei ole
virt-alignment-scan: không tìm thấy lệnh
virt-alignment-scan: komanda nerasta
virt-alignment-scan: Kommando nicht gefunden.
virt-alignment-scan: kommandot finns inte
virt-alignment-scan: komut yok
virt-alignment-scan: nie znaleziono polecenia
virt-alignment-scan: níor aimsíodh an t-ordú
virt-alignment-scan: no se encontró la orden
virt-alignment-scan: no s'ha trobat l'ordre
virt-alignment-scan: opdracht niet gevonden
virt-alignment-scan: parancs nem található
virt-alignment-scan: perintah tidak ditemukan
virt-alignment-scan: príkaz nenájdený
virt-alignment-scan: příkaz nenalezen
virt-alignment-scan: команда не найдена
virt-alignment-scan: командата не е открита
virt-alignment-scan: 命令找不到
virt-alignment-scan: コマンドが見つかりません