thunar-settings: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/thunar-settings - from package: Thunar

You may install the required package with command yum install {package}

On Debian possible default full paths are:

/usr/bin/thunar-settings - from package: Thunar

You may install the required package with command apt-get install {package}
Error in other languages:
thunar-settings: bevel nie gevind nie
thunar-settings: comandă negăsită
thunar-settings: comando não encontrado
thunar-settings: commande introuvable
thunar-settings: command not found
thunar-settings: käsku ei ole
thunar-settings: không tìm thấy lệnh
thunar-settings: komanda nerasta
thunar-settings: Kommando nicht gefunden.
thunar-settings: kommandot finns inte
thunar-settings: komut yok
thunar-settings: nie znaleziono polecenia
thunar-settings: níor aimsíodh an t-ordú
thunar-settings: no se encontró la orden
thunar-settings: no s'ha trobat l'ordre
thunar-settings: opdracht niet gevonden
thunar-settings: parancs nem található
thunar-settings: perintah tidak ditemukan
thunar-settings: príkaz nenájdený
thunar-settings: příkaz nenalezen
thunar-settings: команда не найдена
thunar-settings: командата не е открита
thunar-settings: 命令找不到
thunar-settings: コマンドが見つかりません