system-config-network-cmd: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/system-config-network-cmd - from package: system-config-network-tui
/usr/sbin/system-config-network-cmd - from package: system-config-network-tui

You may install the required package with command yum install {package}
Error in other languages:
system-config-network-cmd: bevel nie gevind nie
system-config-network-cmd: comandă negăsită
system-config-network-cmd: comando não encontrado
system-config-network-cmd: commande introuvable
system-config-network-cmd: command not found
system-config-network-cmd: käsku ei ole
system-config-network-cmd: không tìm thấy lệnh
system-config-network-cmd: komanda nerasta
system-config-network-cmd: Kommando nicht gefunden.
system-config-network-cmd: kommandot finns inte
system-config-network-cmd: komut yok
system-config-network-cmd: nie znaleziono polecenia
system-config-network-cmd: níor aimsíodh an t-ordú
system-config-network-cmd: no se encontró la orden
system-config-network-cmd: no s'ha trobat l'ordre
system-config-network-cmd: opdracht niet gevonden
system-config-network-cmd: parancs nem található
system-config-network-cmd: perintah tidak ditemukan
system-config-network-cmd: príkaz nenájdený
system-config-network-cmd: příkaz nenalezen
system-config-network-cmd: команда не найдена
system-config-network-cmd: командата не е открита
system-config-network-cmd: 命令找不到
system-config-network-cmd: コマンドが見つかりません