sync_members: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/lib/mailman/bin/sync_members - from package: mailman

You may install the required package with command yum install {package}

On Debian possible default full paths are:

/usr/lib/mailman/bin/sync_members - from package: mailman
/usr/sbin/sync_members - from package: mailman

You may install the required package with command apt-get install {package}
Error in other languages:
sync_members: bevel nie gevind nie
sync_members: comandă negăsită
sync_members: comando não encontrado
sync_members: commande introuvable
sync_members: command not found
sync_members: käsku ei ole
sync_members: không tìm thấy lệnh
sync_members: komanda nerasta
sync_members: Kommando nicht gefunden.
sync_members: kommandot finns inte
sync_members: komut yok
sync_members: nie znaleziono polecenia
sync_members: níor aimsíodh an t-ordú
sync_members: no se encontró la orden
sync_members: no s'ha trobat l'ordre
sync_members: opdracht niet gevonden
sync_members: parancs nem található
sync_members: perintah tidak ditemukan
sync_members: príkaz nenájdený
sync_members: příkaz nenalezen
sync_members: команда не найдена
sync_members: командата не е открита
sync_members: 命令找不到
sync_members: コマンドが見つかりません