scotch_dgmap: command not found

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/lib64/mpich/bin/scotch_dgmap - from package: ptscotch-mpich
/usr/lib/mpich/bin/scotch_dgmap - from package: ptscotch-mpich
/usr/lib64/openmpi/bin/scotch_dgmap - from package: ptscotch-openmpi
/usr/lib/openmpi/bin/scotch_dgmap - from package: ptscotch-openmpi

You may install the required package with command yum install {package}

Error in other languages:
scotch_dgmap: bevel nie gevind nie
scotch_dgmap: comandă negăsită
scotch_dgmap: comando não encontrado
scotch_dgmap: commande introuvable
scotch_dgmap: command not found
scotch_dgmap: käsku ei ole
scotch_dgmap: không tìm thấy lệnh
scotch_dgmap: komanda nerasta
scotch_dgmap: Kommando nicht gefunden.
scotch_dgmap: kommandot finns inte
scotch_dgmap: komut yok
scotch_dgmap: nie znaleziono polecenia
scotch_dgmap: níor aimsíodh an t-ordú
scotch_dgmap: no se encontró la orden
scotch_dgmap: no s'ha trobat l'ordre
scotch_dgmap: opdracht niet gevonden
scotch_dgmap: parancs nem található
scotch_dgmap: perintah tidak ditemukan
scotch_dgmap: príkaz nenájdený
scotch_dgmap: příkaz nenalezen
scotch_dgmap: команда не найдена
scotch_dgmap: командата не е открита
scotch_dgmap: 命令找不到
scotch_dgmap: コマンドが見つかりません