scorep-config: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/lib64/mpich/bin/scorep-config - from package: scorep-mpich
/usr/lib64/openmpi/bin/scorep-config - from package: scorep-openmpi
/usr/bin/scorep-config - from package: scorep

You may install the required package with command yum install {package}
Error in other languages:
scorep-config: bevel nie gevind nie
scorep-config: comandă negăsită
scorep-config: comando não encontrado
scorep-config: commande introuvable
scorep-config: command not found
scorep-config: käsku ei ole
scorep-config: không tìm thấy lệnh
scorep-config: komanda nerasta
scorep-config: Kommando nicht gefunden.
scorep-config: kommandot finns inte
scorep-config: komut yok
scorep-config: nie znaleziono polecenia
scorep-config: níor aimsíodh an t-ordú
scorep-config: no se encontró la orden
scorep-config: no s'ha trobat l'ordre
scorep-config: opdracht niet gevonden
scorep-config: parancs nem található
scorep-config: perintah tidak ditemukan
scorep-config: príkaz nenájdený
scorep-config: příkaz nenalezen
scorep-config: команда не найдена
scorep-config: командата не е открита
scorep-config: 命令找不到
scorep-config: コマンドが見つかりません