rtl_fm: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/bin/rtl_fm - from package: rtl-sdr

You may install the required package with command apt-get install {package}
Error in other languages:
rtl_fm: bevel nie gevind nie
rtl_fm: comandă negăsită
rtl_fm: comando não encontrado
rtl_fm: commande introuvable
rtl_fm: command not found
rtl_fm: käsku ei ole
rtl_fm: không tìm thấy lệnh
rtl_fm: komanda nerasta
rtl_fm: Kommando nicht gefunden.
rtl_fm: kommandot finns inte
rtl_fm: komut yok
rtl_fm: nie znaleziono polecenia
rtl_fm: níor aimsíodh an t-ordú
rtl_fm: no se encontró la orden
rtl_fm: no s'ha trobat l'ordre
rtl_fm: opdracht niet gevonden
rtl_fm: parancs nem található
rtl_fm: perintah tidak ditemukan
rtl_fm: príkaz nenájdený
rtl_fm: příkaz nenalezen
rtl_fm: команда не найдена
rtl_fm: командата не е открита
rtl_fm: 命令找不到
rtl_fm: コマンドが見つかりません