relion_particle_polish: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/bin/relion_particle_polish - from package: relion-bin+gui
/usr/bin/relion_particle_polish - from package: relion-bin+mpi+gui
/usr/bin/relion_particle_polish - from package: relion-bin+mpi
/usr/bin/relion_particle_polish - from package: relion-bin

You may install the required package with command apt-get install {package}
Error in other languages:
relion_particle_polish: bevel nie gevind nie
relion_particle_polish: comandă negăsită
relion_particle_polish: comando não encontrado
relion_particle_polish: commande introuvable
relion_particle_polish: command not found
relion_particle_polish: käsku ei ole
relion_particle_polish: không tìm thấy lệnh
relion_particle_polish: komanda nerasta
relion_particle_polish: Kommando nicht gefunden.
relion_particle_polish: kommandot finns inte
relion_particle_polish: komut yok
relion_particle_polish: nie znaleziono polecenia
relion_particle_polish: níor aimsíodh an t-ordú
relion_particle_polish: no se encontró la orden
relion_particle_polish: no s'ha trobat l'ordre
relion_particle_polish: opdracht niet gevonden
relion_particle_polish: parancs nem található
relion_particle_polish: perintah tidak ditemukan
relion_particle_polish: príkaz nenájdený
relion_particle_polish: příkaz nenalezen
relion_particle_polish: команда не найдена
relion_particle_polish: командата не е открита
relion_particle_polish: 命令找不到
relion_particle_polish: コマンドが見つかりません