qmail-pop3d: command not found

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/sbin/qmail-pop3d - from package: qmail
/var/lib/qmail/bin/qmail-pop3d - from package: qmail

You may install the required package with command apt-get install {package}

Error in other languages:
qmail-pop3d: bevel nie gevind nie
qmail-pop3d: comandă negăsită
qmail-pop3d: comando não encontrado
qmail-pop3d: commande introuvable
qmail-pop3d: command not found
qmail-pop3d: käsku ei ole
qmail-pop3d: không tìm thấy lệnh
qmail-pop3d: komanda nerasta
qmail-pop3d: Kommando nicht gefunden.
qmail-pop3d: kommandot finns inte
qmail-pop3d: komut yok
qmail-pop3d: nie znaleziono polecenia
qmail-pop3d: níor aimsíodh an t-ordú
qmail-pop3d: no se encontró la orden
qmail-pop3d: no s'ha trobat l'ordre
qmail-pop3d: opdracht niet gevonden
qmail-pop3d: parancs nem található
qmail-pop3d: perintah tidak ditemukan
qmail-pop3d: príkaz nenájdený
qmail-pop3d: příkaz nenalezen
qmail-pop3d: команда не найдена
qmail-pop3d: командата не е открита
qmail-pop3d: 命令找不到
qmail-pop3d: コマンドが見つかりません