pyalacarte: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/pyalacarte - from package: wxPython

You may install the required package with command yum install {package}

On Debian possible default full paths are:

/usr/bin/pyalacarte - from package: python-wxtools

You may install the required package with command apt-get install {package}
Error in other languages:
pyalacarte: bevel nie gevind nie
pyalacarte: comandă negăsită
pyalacarte: comando não encontrado
pyalacarte: commande introuvable
pyalacarte: command not found
pyalacarte: käsku ei ole
pyalacarte: không tìm thấy lệnh
pyalacarte: komanda nerasta
pyalacarte: Kommando nicht gefunden.
pyalacarte: kommandot finns inte
pyalacarte: komut yok
pyalacarte: nie znaleziono polecenia
pyalacarte: níor aimsíodh an t-ordú
pyalacarte: no se encontró la orden
pyalacarte: no s'ha trobat l'ordre
pyalacarte: opdracht niet gevonden
pyalacarte: parancs nem található
pyalacarte: perintah tidak ditemukan
pyalacarte: príkaz nenájdený
pyalacarte: příkaz nenalezen
pyalacarte: команда не найдена
pyalacarte: командата не е открита
pyalacarte: 命令找不到
pyalacarte: コマンドが見つかりません