pwsafe: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/pwsafe - from package: pwsafe

You may install the required package with command yum install {package}
Error in other languages:
pwsafe: bevel nie gevind nie
pwsafe: comandă negăsită
pwsafe: comando não encontrado
pwsafe: commande introuvable
pwsafe: command not found
pwsafe: käsku ei ole
pwsafe: không tìm thấy lệnh
pwsafe: komanda nerasta
pwsafe: Kommando nicht gefunden.
pwsafe: kommandot finns inte
pwsafe: komut yok
pwsafe: nie znaleziono polecenia
pwsafe: níor aimsíodh an t-ordú
pwsafe: no se encontró la orden
pwsafe: no s'ha trobat l'ordre
pwsafe: opdracht niet gevonden
pwsafe: parancs nem található
pwsafe: perintah tidak ditemukan
pwsafe: príkaz nenájdený
pwsafe: příkaz nenalezen
pwsafe: команда не найдена
pwsafe: командата не е открита
pwsafe: 命令找不到
pwsafe: コマンドが見つかりません