pvbatch_openmpi: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/lib64/openmpi/bin/pvbatch_openmpi - from package: paraview-openmpi

You may install the required package with command yum install {package}
Error in other languages:
pvbatch_openmpi: bevel nie gevind nie
pvbatch_openmpi: comandă negăsită
pvbatch_openmpi: comando não encontrado
pvbatch_openmpi: commande introuvable
pvbatch_openmpi: command not found
pvbatch_openmpi: käsku ei ole
pvbatch_openmpi: không tìm thấy lệnh
pvbatch_openmpi: komanda nerasta
pvbatch_openmpi: Kommando nicht gefunden.
pvbatch_openmpi: kommandot finns inte
pvbatch_openmpi: komut yok
pvbatch_openmpi: nie znaleziono polecenia
pvbatch_openmpi: níor aimsíodh an t-ordú
pvbatch_openmpi: no se encontró la orden
pvbatch_openmpi: no s'ha trobat l'ordre
pvbatch_openmpi: opdracht niet gevonden
pvbatch_openmpi: parancs nem található
pvbatch_openmpi: perintah tidak ditemukan
pvbatch_openmpi: príkaz nenájdený
pvbatch_openmpi: příkaz nenalezen
pvbatch_openmpi: команда не найдена
pvbatch_openmpi: командата не е открита
pvbatch_openmpi: 命令找不到
pvbatch_openmpi: コマンドが見つかりません