psiblast: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/bin/psiblast - from package: ncbi-blast+

You may install the required package with command apt-get install {package}
Error in other languages:
psiblast: bevel nie gevind nie
psiblast: comandă negăsită
psiblast: comando não encontrado
psiblast: commande introuvable
psiblast: command not found
psiblast: käsku ei ole
psiblast: không tìm thấy lệnh
psiblast: komanda nerasta
psiblast: Kommando nicht gefunden.
psiblast: kommandot finns inte
psiblast: komut yok
psiblast: nie znaleziono polecenia
psiblast: níor aimsíodh an t-ordú
psiblast: no se encontró la orden
psiblast: no s'ha trobat l'ordre
psiblast: opdracht niet gevonden
psiblast: parancs nem található
psiblast: perintah tidak ditemukan
psiblast: príkaz nenájdený
psiblast: příkaz nenalezen
psiblast: команда не найдена
psiblast: командата не е открита
psiblast: 命令找不到
psiblast: コマンドが見つかりません