pppoe-sniff: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/sbin/pppoe-sniff - from package: rp-pppoe
/usr/sbin/pppoe-sniff - from package: rp-pppoe

You may install the required package with command yum install {package}

On Debian possible default full paths are:

/usr/sbin/pppoe-sniff - from package: pppoe

You may install the required package with command apt-get install {package}
Error in other languages:
pppoe-sniff: bevel nie gevind nie
pppoe-sniff: comandă negăsită
pppoe-sniff: comando não encontrado
pppoe-sniff: commande introuvable
pppoe-sniff: command not found
pppoe-sniff: käsku ei ole
pppoe-sniff: không tìm thấy lệnh
pppoe-sniff: komanda nerasta
pppoe-sniff: Kommando nicht gefunden.
pppoe-sniff: kommandot finns inte
pppoe-sniff: komut yok
pppoe-sniff: nie znaleziono polecenia
pppoe-sniff: níor aimsíodh an t-ordú
pppoe-sniff: no se encontró la orden
pppoe-sniff: no s'ha trobat l'ordre
pppoe-sniff: opdracht niet gevonden
pppoe-sniff: parancs nem található
pppoe-sniff: perintah tidak ditemukan
pppoe-sniff: príkaz nenájdený
pppoe-sniff: příkaz nenalezen
pppoe-sniff: команда не найдена
pppoe-sniff: командата не е открита
pppoe-sniff: 命令找不到
pppoe-sniff: コマンドが見つかりません