nysynopt-gfortran: command not found

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/nysynopt-gfortran - from package: patchy-gfortran

You may install the required package with command yum install {package}

Error in other languages:
nysynopt-gfortran: bevel nie gevind nie
nysynopt-gfortran: comandă negăsită
nysynopt-gfortran: comando não encontrado
nysynopt-gfortran: commande introuvable
nysynopt-gfortran: command not found
nysynopt-gfortran: käsku ei ole
nysynopt-gfortran: không tìm thấy lệnh
nysynopt-gfortran: komanda nerasta
nysynopt-gfortran: Kommando nicht gefunden.
nysynopt-gfortran: kommandot finns inte
nysynopt-gfortran: komut yok
nysynopt-gfortran: nie znaleziono polecenia
nysynopt-gfortran: níor aimsíodh an t-ordú
nysynopt-gfortran: no se encontró la orden
nysynopt-gfortran: no s'ha trobat l'ordre
nysynopt-gfortran: opdracht niet gevonden
nysynopt-gfortran: parancs nem található
nysynopt-gfortran: perintah tidak ditemukan
nysynopt-gfortran: príkaz nenájdený
nysynopt-gfortran: příkaz nenalezen
nysynopt-gfortran: команда не найдена
nysynopt-gfortran: командата не е открита
nysynopt-gfortran: 命令找不到
nysynopt-gfortran: コマンドが見つかりません