nrsysmond: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/sbin/nrsysmond - from package: newrelic-sysmond

You may install the required package with command yum install {package}
Error in other languages:
nrsysmond: bevel nie gevind nie
nrsysmond: comandă negăsită
nrsysmond: comando não encontrado
nrsysmond: commande introuvable
nrsysmond: command not found
nrsysmond: käsku ei ole
nrsysmond: không tìm thấy lệnh
nrsysmond: komanda nerasta
nrsysmond: Kommando nicht gefunden.
nrsysmond: kommandot finns inte
nrsysmond: komut yok
nrsysmond: nie znaleziono polecenia
nrsysmond: níor aimsíodh an t-ordú
nrsysmond: no se encontró la orden
nrsysmond: no s'ha trobat l'ordre
nrsysmond: opdracht niet gevonden
nrsysmond: parancs nem található
nrsysmond: perintah tidak ditemukan
nrsysmond: príkaz nenájdený
nrsysmond: příkaz nenalezen
nrsysmond: команда не найдена
nrsysmond: командата не е открита
nrsysmond: 命令找不到
nrsysmond: コマンドが見つかりません