nfsiostat: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/sbin/nfsiostat - from package: nfs-utils

You may install the required package with command yum install {package}

On Debian possible default full paths are:

/usr/sbin/nfsiostat - from package: nfs-common

You may install the required package with command apt-get install {package}
Error in other languages:
nfsiostat: bevel nie gevind nie
nfsiostat: comandă negăsită
nfsiostat: comando não encontrado
nfsiostat: commande introuvable
nfsiostat: command not found
nfsiostat: käsku ei ole
nfsiostat: không tìm thấy lệnh
nfsiostat: komanda nerasta
nfsiostat: Kommando nicht gefunden.
nfsiostat: kommandot finns inte
nfsiostat: komut yok
nfsiostat: nie znaleziono polecenia
nfsiostat: níor aimsíodh an t-ordú
nfsiostat: no se encontró la orden
nfsiostat: no s'ha trobat l'ordre
nfsiostat: opdracht niet gevonden
nfsiostat: parancs nem található
nfsiostat: perintah tidak ditemukan
nfsiostat: príkaz nenájdený
nfsiostat: příkaz nenalezen
nfsiostat: команда не найдена
nfsiostat: командата не е открита
nfsiostat: 命令找不到
nfsiostat: コマンドが見つかりません