mpireconfig: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/lib64/mvapich-psm/bin/mpireconfig - from package: mvapich-psm
/usr/lib64/mvapich/bin/mpireconfig - from package: mvapich
/usr/lib/mvapich/bin/mpireconfig - from package: mvapich

You may install the required package with command yum install {package}
Error in other languages:
mpireconfig: bevel nie gevind nie
mpireconfig: comandă negăsită
mpireconfig: comando não encontrado
mpireconfig: commande introuvable
mpireconfig: command not found
mpireconfig: käsku ei ole
mpireconfig: không tìm thấy lệnh
mpireconfig: komanda nerasta
mpireconfig: Kommando nicht gefunden.
mpireconfig: kommandot finns inte
mpireconfig: komut yok
mpireconfig: nie znaleziono polecenia
mpireconfig: níor aimsíodh an t-ordú
mpireconfig: no se encontró la orden
mpireconfig: no s'ha trobat l'ordre
mpireconfig: opdracht niet gevonden
mpireconfig: parancs nem található
mpireconfig: perintah tidak ditemukan
mpireconfig: príkaz nenájdený
mpireconfig: příkaz nenalezen
mpireconfig: команда не найдена
mpireconfig: командата не е открита
mpireconfig: 命令找不到
mpireconfig: コマンドが見つかりません