mpi_assign: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/bin/mpi_assign - from package: mpikmeans-tools

You may install the required package with command apt-get install {package}
Error in other languages:
mpi_assign: bevel nie gevind nie
mpi_assign: comandă negăsită
mpi_assign: comando não encontrado
mpi_assign: commande introuvable
mpi_assign: command not found
mpi_assign: käsku ei ole
mpi_assign: không tìm thấy lệnh
mpi_assign: komanda nerasta
mpi_assign: Kommando nicht gefunden.
mpi_assign: kommandot finns inte
mpi_assign: komut yok
mpi_assign: nie znaleziono polecenia
mpi_assign: níor aimsíodh an t-ordú
mpi_assign: no se encontró la orden
mpi_assign: no s'ha trobat l'ordre
mpi_assign: opdracht niet gevonden
mpi_assign: parancs nem található
mpi_assign: perintah tidak ditemukan
mpi_assign: príkaz nenájdený
mpi_assign: příkaz nenalezen
mpi_assign: команда не найдена
mpi_assign: командата не е открита
mpi_assign: 命令找不到
mpi_assign: コマンドが見つかりません