i686-w64-mingw32-c++: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/i686-w64-mingw32-c++ - from package: mingw32-gcc-c++

You may install the required package with command yum install {package}
Error in other languages:
i686-w64-mingw32-c++: bevel nie gevind nie
i686-w64-mingw32-c++: comandă negăsită
i686-w64-mingw32-c++: comando não encontrado
i686-w64-mingw32-c++: commande introuvable
i686-w64-mingw32-c++: command not found
i686-w64-mingw32-c++: käsku ei ole
i686-w64-mingw32-c++: không tìm thấy lệnh
i686-w64-mingw32-c++: komanda nerasta
i686-w64-mingw32-c++: Kommando nicht gefunden.
i686-w64-mingw32-c++: kommandot finns inte
i686-w64-mingw32-c++: komut yok
i686-w64-mingw32-c++: nie znaleziono polecenia
i686-w64-mingw32-c++: níor aimsíodh an t-ordú
i686-w64-mingw32-c++: no se encontró la orden
i686-w64-mingw32-c++: no s'ha trobat l'ordre
i686-w64-mingw32-c++: opdracht niet gevonden
i686-w64-mingw32-c++: parancs nem található
i686-w64-mingw32-c++: perintah tidak ditemukan
i686-w64-mingw32-c++: príkaz nenájdený
i686-w64-mingw32-c++: příkaz nenalezen
i686-w64-mingw32-c++: команда не найдена
i686-w64-mingw32-c++: командата не е открита
i686-w64-mingw32-c++: 命令找不到
i686-w64-mingw32-c++: コマンドが見つかりません