hp_syn_alm_cxx: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/hp_syn_alm_cxx - from package: healpix-c++

You may install the required package with command yum install {package}
Error in other languages:
hp_syn_alm_cxx: bevel nie gevind nie
hp_syn_alm_cxx: comandă negăsită
hp_syn_alm_cxx: comando não encontrado
hp_syn_alm_cxx: commande introuvable
hp_syn_alm_cxx: command not found
hp_syn_alm_cxx: käsku ei ole
hp_syn_alm_cxx: không tìm thấy lệnh
hp_syn_alm_cxx: komanda nerasta
hp_syn_alm_cxx: Kommando nicht gefunden.
hp_syn_alm_cxx: kommandot finns inte
hp_syn_alm_cxx: komut yok
hp_syn_alm_cxx: nie znaleziono polecenia
hp_syn_alm_cxx: níor aimsíodh an t-ordú
hp_syn_alm_cxx: no se encontró la orden
hp_syn_alm_cxx: no s'ha trobat l'ordre
hp_syn_alm_cxx: opdracht niet gevonden
hp_syn_alm_cxx: parancs nem található
hp_syn_alm_cxx: perintah tidak ditemukan
hp_syn_alm_cxx: príkaz nenájdený
hp_syn_alm_cxx: příkaz nenalezen
hp_syn_alm_cxx: команда не найдена
hp_syn_alm_cxx: командата не е открита
hp_syn_alm_cxx: 命令找不到
hp_syn_alm_cxx: コマンドが見つかりません