gtkdoc-mkman: command not found

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/gtkdoc-mkman - from package: gtk-doc

You may install the required package with command yum install {package}

On Debian possible default full paths are:

/usr/bin/gtkdoc-mkman - from package: gtk-doc-tools

You may install the required package with command apt-get install {package}

Error in other languages:
gtkdoc-mkman: bevel nie gevind nie
gtkdoc-mkman: comandă negăsită
gtkdoc-mkman: comando não encontrado
gtkdoc-mkman: commande introuvable
gtkdoc-mkman: command not found
gtkdoc-mkman: käsku ei ole
gtkdoc-mkman: không tìm thấy lệnh
gtkdoc-mkman: komanda nerasta
gtkdoc-mkman: Kommando nicht gefunden.
gtkdoc-mkman: kommandot finns inte
gtkdoc-mkman: komut yok
gtkdoc-mkman: nie znaleziono polecenia
gtkdoc-mkman: níor aimsíodh an t-ordú
gtkdoc-mkman: no se encontró la orden
gtkdoc-mkman: no s'ha trobat l'ordre
gtkdoc-mkman: opdracht niet gevonden
gtkdoc-mkman: parancs nem található
gtkdoc-mkman: perintah tidak ditemukan
gtkdoc-mkman: príkaz nenájdený
gtkdoc-mkman: příkaz nenalezen
gtkdoc-mkman: команда не найдена
gtkdoc-mkman: командата не е открита
gtkdoc-mkman: 命令找不到
gtkdoc-mkman: コマンドが見つかりません