gtk-redshift: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/gtk-redshift - from package: gtk-redshift

You may install the required package with command yum install {package}
Error in other languages:
gtk-redshift: bevel nie gevind nie
gtk-redshift: comandă negăsită
gtk-redshift: comando não encontrado
gtk-redshift: commande introuvable
gtk-redshift: command not found
gtk-redshift: käsku ei ole
gtk-redshift: không tìm thấy lệnh
gtk-redshift: komanda nerasta
gtk-redshift: Kommando nicht gefunden.
gtk-redshift: kommandot finns inte
gtk-redshift: komut yok
gtk-redshift: nie znaleziono polecenia
gtk-redshift: níor aimsíodh an t-ordú
gtk-redshift: no se encontró la orden
gtk-redshift: no s'ha trobat l'ordre
gtk-redshift: opdracht niet gevonden
gtk-redshift: parancs nem található
gtk-redshift: perintah tidak ditemukan
gtk-redshift: príkaz nenájdený
gtk-redshift: příkaz nenalezen
gtk-redshift: команда не найдена
gtk-redshift: командата не е открита
gtk-redshift: 命令找不到
gtk-redshift: コマンドが見つかりません