g_msd: command not found

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/g_msd - from package: gromacs

You may install the required package with command yum install {package}

On Debian possible default full paths are:

/usr/bin/g_msd - from package: gromacs

You may install the required package with command apt-get install {package}

Error in other languages:
g_msd: bevel nie gevind nie
g_msd: comandă negăsită
g_msd: comando não encontrado
g_msd: commande introuvable
g_msd: command not found
g_msd: käsku ei ole
g_msd: không tìm thấy lệnh
g_msd: komanda nerasta
g_msd: Kommando nicht gefunden.
g_msd: kommandot finns inte
g_msd: komut yok
g_msd: nie znaleziono polecenia
g_msd: níor aimsíodh an t-ordú
g_msd: no se encontró la orden
g_msd: no s'ha trobat l'ordre
g_msd: opdracht niet gevonden
g_msd: parancs nem található
g_msd: perintah tidak ditemukan
g_msd: príkaz nenájdený
g_msd: příkaz nenalezen
g_msd: команда не найдена
g_msd: командата не е открита
g_msd: 命令找不到
g_msd: コマンドが見つかりません