freeDiameterd: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/freeDiameterd - from package: freeDiameter

You may install the required package with command yum install {package}
Error in other languages:
freeDiameterd: bevel nie gevind nie
freeDiameterd: comandă negăsită
freeDiameterd: comando não encontrado
freeDiameterd: commande introuvable
freeDiameterd: command not found
freeDiameterd: käsku ei ole
freeDiameterd: không tìm thấy lệnh
freeDiameterd: komanda nerasta
freeDiameterd: Kommando nicht gefunden.
freeDiameterd: kommandot finns inte
freeDiameterd: komut yok
freeDiameterd: nie znaleziono polecenia
freeDiameterd: níor aimsíodh an t-ordú
freeDiameterd: no se encontró la orden
freeDiameterd: no s'ha trobat l'ordre
freeDiameterd: opdracht niet gevonden
freeDiameterd: parancs nem található
freeDiameterd: perintah tidak ditemukan
freeDiameterd: príkaz nenájdený
freeDiameterd: příkaz nenalezen
freeDiameterd: команда не найдена
freeDiameterd: командата не е открита
freeDiameterd: 命令找不到
freeDiameterd: コマンドが見つかりません