ffconfiggui: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/ffconfiggui - from package: fawkes-guis

You may install the required package with command yum install {package}
Error in other languages:
ffconfiggui: bevel nie gevind nie
ffconfiggui: comandă negăsită
ffconfiggui: comando não encontrado
ffconfiggui: commande introuvable
ffconfiggui: command not found
ffconfiggui: käsku ei ole
ffconfiggui: không tìm thấy lệnh
ffconfiggui: komanda nerasta
ffconfiggui: Kommando nicht gefunden.
ffconfiggui: kommandot finns inte
ffconfiggui: komut yok
ffconfiggui: nie znaleziono polecenia
ffconfiggui: níor aimsíodh an t-ordú
ffconfiggui: no se encontró la orden
ffconfiggui: no s'ha trobat l'ordre
ffconfiggui: opdracht niet gevonden
ffconfiggui: parancs nem található
ffconfiggui: perintah tidak ditemukan
ffconfiggui: príkaz nenájdený
ffconfiggui: příkaz nenalezen
ffconfiggui: команда не найдена
ffconfiggui: командата не е открита
ffconfiggui: 命令找不到
ffconfiggui: コマンドが見つかりません