docco: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/docco - from package: docco
/usr/lib/node_modules/docco/bin/docco - from package: docco

You may install the required package with command yum install {package}
Error in other languages:
docco: bevel nie gevind nie
docco: comandă negăsită
docco: comando não encontrado
docco: commande introuvable
docco: command not found
docco: käsku ei ole
docco: không tìm thấy lệnh
docco: komanda nerasta
docco: Kommando nicht gefunden.
docco: kommandot finns inte
docco: komut yok
docco: nie znaleziono polecenia
docco: níor aimsíodh an t-ordú
docco: no se encontró la orden
docco: no s'ha trobat l'ordre
docco: opdracht niet gevonden
docco: parancs nem található
docco: perintah tidak ditemukan
docco: príkaz nenájdený
docco: příkaz nenalezen
docco: команда не найдена
docco: командата не е открита
docco: 命令找不到
docco: コマンドが見つかりません