dcm2nii: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/bin/dcm2nii - from package: mricron

You may install the required package with command apt-get install {package}
Error in other languages:
dcm2nii: bevel nie gevind nie
dcm2nii: comandă negăsită
dcm2nii: comando não encontrado
dcm2nii: commande introuvable
dcm2nii: command not found
dcm2nii: käsku ei ole
dcm2nii: không tìm thấy lệnh
dcm2nii: komanda nerasta
dcm2nii: Kommando nicht gefunden.
dcm2nii: kommandot finns inte
dcm2nii: komut yok
dcm2nii: nie znaleziono polecenia
dcm2nii: níor aimsíodh an t-ordú
dcm2nii: no se encontró la orden
dcm2nii: no s'ha trobat l'ordre
dcm2nii: opdracht niet gevonden
dcm2nii: parancs nem található
dcm2nii: perintah tidak ditemukan
dcm2nii: príkaz nenájdený
dcm2nii: příkaz nenalezen
dcm2nii: команда не найдена
dcm2nii: командата не е открита
dcm2nii: 命令找不到
dcm2nii: コマンドが見つかりません