darkplaces-quake-glx: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/darkplaces-quake-glx - from package: darkplaces-quake

You may install the required package with command yum install {package}
Error in other languages:
darkplaces-quake-glx: bevel nie gevind nie
darkplaces-quake-glx: comandă negăsită
darkplaces-quake-glx: comando não encontrado
darkplaces-quake-glx: commande introuvable
darkplaces-quake-glx: command not found
darkplaces-quake-glx: käsku ei ole
darkplaces-quake-glx: không tìm thấy lệnh
darkplaces-quake-glx: komanda nerasta
darkplaces-quake-glx: Kommando nicht gefunden.
darkplaces-quake-glx: kommandot finns inte
darkplaces-quake-glx: komut yok
darkplaces-quake-glx: nie znaleziono polecenia
darkplaces-quake-glx: níor aimsíodh an t-ordú
darkplaces-quake-glx: no se encontró la orden
darkplaces-quake-glx: no s'ha trobat l'ordre
darkplaces-quake-glx: opdracht niet gevonden
darkplaces-quake-glx: parancs nem található
darkplaces-quake-glx: perintah tidak ditemukan
darkplaces-quake-glx: príkaz nenájdený
darkplaces-quake-glx: příkaz nenalezen
darkplaces-quake-glx: команда не найдена
darkplaces-quake-glx: командата не е открита
darkplaces-quake-glx: 命令找不到
darkplaces-quake-glx: コマンドが見つかりません