bcopy.postgresql: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/sbin/bcopy.postgresql - from package: bacula-storage-postgresql

You may install the required package with command yum install {package}
Error in other languages:
bcopy.postgresql: bevel nie gevind nie
bcopy.postgresql: comandă negăsită
bcopy.postgresql: comando não encontrado
bcopy.postgresql: commande introuvable
bcopy.postgresql: command not found
bcopy.postgresql: käsku ei ole
bcopy.postgresql: không tìm thấy lệnh
bcopy.postgresql: komanda nerasta
bcopy.postgresql: Kommando nicht gefunden.
bcopy.postgresql: kommandot finns inte
bcopy.postgresql: komut yok
bcopy.postgresql: nie znaleziono polecenia
bcopy.postgresql: níor aimsíodh an t-ordú
bcopy.postgresql: no se encontró la orden
bcopy.postgresql: no s'ha trobat l'ordre
bcopy.postgresql: opdracht niet gevonden
bcopy.postgresql: parancs nem található
bcopy.postgresql: perintah tidak ditemukan
bcopy.postgresql: príkaz nenájdený
bcopy.postgresql: příkaz nenalezen
bcopy.postgresql: команда не найдена
bcopy.postgresql: командата не е открита
bcopy.postgresql: 命令找不到
bcopy.postgresql: コマンドが見つかりません