apbs-smooth: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/apbs-smooth - from package: apbs-tools

You may install the required package with command yum install {package}
Error in other languages:
apbs-smooth: bevel nie gevind nie
apbs-smooth: comandă negăsită
apbs-smooth: comando não encontrado
apbs-smooth: commande introuvable
apbs-smooth: command not found
apbs-smooth: käsku ei ole
apbs-smooth: không tìm thấy lệnh
apbs-smooth: komanda nerasta
apbs-smooth: Kommando nicht gefunden.
apbs-smooth: kommandot finns inte
apbs-smooth: komut yok
apbs-smooth: nie znaleziono polecenia
apbs-smooth: níor aimsíodh an t-ordú
apbs-smooth: no se encontró la orden
apbs-smooth: no s'ha trobat l'ordre
apbs-smooth: opdracht niet gevonden
apbs-smooth: parancs nem található
apbs-smooth: perintah tidak ditemukan
apbs-smooth: príkaz nenájdený
apbs-smooth: příkaz nenalezen
apbs-smooth: команда не найдена
apbs-smooth: командата не е открита
apbs-smooth: 命令找不到
apbs-smooth: コマンドが見つかりません