MapAlignerSpectrum: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/bin/MapAlignerSpectrum - from package: topp

You may install the required package with command apt-get install {package}
Error in other languages:
MapAlignerSpectrum: bevel nie gevind nie
MapAlignerSpectrum: comandă negăsită
MapAlignerSpectrum: comando não encontrado
MapAlignerSpectrum: commande introuvable
MapAlignerSpectrum: command not found
MapAlignerSpectrum: käsku ei ole
MapAlignerSpectrum: không tìm thấy lệnh
MapAlignerSpectrum: komanda nerasta
MapAlignerSpectrum: Kommando nicht gefunden.
MapAlignerSpectrum: kommandot finns inte
MapAlignerSpectrum: komut yok
MapAlignerSpectrum: nie znaleziono polecenia
MapAlignerSpectrum: níor aimsíodh an t-ordú
MapAlignerSpectrum: no se encontró la orden
MapAlignerSpectrum: no s'ha trobat l'ordre
MapAlignerSpectrum: opdracht niet gevonden
MapAlignerSpectrum: parancs nem található
MapAlignerSpectrum: perintah tidak ditemukan
MapAlignerSpectrum: príkaz nenájdený
MapAlignerSpectrum: příkaz nenalezen
MapAlignerSpectrum: команда не найдена
MapAlignerSpectrum: командата не е открита
MapAlignerSpectrum: 命令找不到
MapAlignerSpectrum: コマンドが見つかりません