relion_stack_create: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/bin/relion_stack_create - from package: relion-bin+gui
/usr/bin/relion_stack_create - from package: relion-bin+mpi+gui
/usr/bin/relion_stack_create - from package: relion-bin+mpi
/usr/bin/relion_stack_create - from package: relion-bin

You may install the required package with command apt-get install {package}
Error in other languages:
relion_stack_create: bevel nie gevind nie
relion_stack_create: comandă negăsită
relion_stack_create: comando não encontrado
relion_stack_create: commande introuvable
relion_stack_create: command not found
relion_stack_create: käsku ei ole
relion_stack_create: không tìm thấy lệnh
relion_stack_create: komanda nerasta
relion_stack_create: Kommando nicht gefunden.
relion_stack_create: kommandot finns inte
relion_stack_create: komut yok
relion_stack_create: nie znaleziono polecenia
relion_stack_create: níor aimsíodh an t-ordú
relion_stack_create: no se encontró la orden
relion_stack_create: no s'ha trobat l'ordre
relion_stack_create: opdracht niet gevonden
relion_stack_create: parancs nem található
relion_stack_create: perintah tidak ditemukan
relion_stack_create: príkaz nenájdený
relion_stack_create: příkaz nenalezen
relion_stack_create: команда не найдена
relion_stack_create: командата не е открита
relion_stack_create: 命令找不到
relion_stack_create: コマンドが見つかりません