xca: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/bin/xca - from package: xca

You may install the required package with command apt-get install {package}
Error in other languages:
xca: bevel nie gevind nie
xca: comandă negăsită
xca: comando não encontrado
xca: commande introuvable
xca: command not found
xca: käsku ei ole
xca: không tìm thấy lệnh
xca: komanda nerasta
xca: Kommando nicht gefunden.
xca: kommandot finns inte
xca: komut yok
xca: nie znaleziono polecenia
xca: níor aimsíodh an t-ordú
xca: no se encontró la orden
xca: no s'ha trobat l'ordre
xca: opdracht niet gevonden
xca: parancs nem található
xca: perintah tidak ditemukan
xca: príkaz nenájdený
xca: příkaz nenalezen
xca: команда не найдена
xca: командата не е открита
xca: 命令找不到
xca: コマンドが見つかりません