smbldap-populate: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/sbin/smbldap-populate - from package: smbldap-tools

You may install the required package with command yum install {package}

On Debian possible default full paths are:

/usr/sbin/smbldap-populate - from package: smbldap-tools

You may install the required package with command apt-get install {package}
Error in other languages:
smbldap-populate: bevel nie gevind nie
smbldap-populate: comandă negăsită
smbldap-populate: comando não encontrado
smbldap-populate: commande introuvable
smbldap-populate: command not found
smbldap-populate: käsku ei ole
smbldap-populate: không tìm thấy lệnh
smbldap-populate: komanda nerasta
smbldap-populate: Kommando nicht gefunden.
smbldap-populate: kommandot finns inte
smbldap-populate: komut yok
smbldap-populate: nie znaleziono polecenia
smbldap-populate: níor aimsíodh an t-ordú
smbldap-populate: no se encontró la orden
smbldap-populate: no s'ha trobat l'ordre
smbldap-populate: opdracht niet gevonden
smbldap-populate: parancs nem található
smbldap-populate: perintah tidak ditemukan
smbldap-populate: príkaz nenájdený
smbldap-populate: příkaz nenalezen
smbldap-populate: команда не найдена
smbldap-populate: командата не е открита
smbldap-populate: 命令找不到
smbldap-populate: コマンドが見つかりません