pop3d-ssl: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/sbin/pop3d-ssl - from package: courier-pop-ssl

You may install the required package with command apt-get install {package}
Error in other languages:
pop3d-ssl: bevel nie gevind nie
pop3d-ssl: comandă negăsită
pop3d-ssl: comando não encontrado
pop3d-ssl: commande introuvable
pop3d-ssl: command not found
pop3d-ssl: käsku ei ole
pop3d-ssl: không tìm thấy lệnh
pop3d-ssl: komanda nerasta
pop3d-ssl: Kommando nicht gefunden.
pop3d-ssl: kommandot finns inte
pop3d-ssl: komut yok
pop3d-ssl: nie znaleziono polecenia
pop3d-ssl: níor aimsíodh an t-ordú
pop3d-ssl: no se encontró la orden
pop3d-ssl: no s'ha trobat l'ordre
pop3d-ssl: opdracht niet gevonden
pop3d-ssl: parancs nem található
pop3d-ssl: perintah tidak ditemukan
pop3d-ssl: príkaz nenájdený
pop3d-ssl: příkaz nenalezen
pop3d-ssl: команда не найдена
pop3d-ssl: командата не е открита
pop3d-ssl: 命令找不到
pop3d-ssl: コマンドが見つかりません