opxdvi: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/opxdvi - from package: xdvik

You may install the required package with command yum install {package}
Error in other languages:
opxdvi: bevel nie gevind nie
opxdvi: comandă negăsită
opxdvi: comando não encontrado
opxdvi: commande introuvable
opxdvi: command not found
opxdvi: käsku ei ole
opxdvi: không tìm thấy lệnh
opxdvi: komanda nerasta
opxdvi: Kommando nicht gefunden.
opxdvi: kommandot finns inte
opxdvi: komut yok
opxdvi: nie znaleziono polecenia
opxdvi: níor aimsíodh an t-ordú
opxdvi: no se encontró la orden
opxdvi: no s'ha trobat l'ordre
opxdvi: opdracht niet gevonden
opxdvi: parancs nem található
opxdvi: perintah tidak ditemukan
opxdvi: príkaz nenájdený
opxdvi: příkaz nenalezen
opxdvi: команда не найдена
opxdvi: командата не е открита
opxdvi: 命令找不到
opxdvi: コマンドが見つかりません